Battery-type and binder-free MgCo2O4-NWs@NF electrode materials for the assembly of advanced hybrid supercapacitors |
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Affiliation: | 1. School of Materials Science and Engineering, North University of China, Taiyuan 030051, China;2. College of Resources and Environment, Shandong Agricultural University, Tai''an 271018, China;3. School of Energy and Power Engineering, North University of China, Taiyuan 030051, China |
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Abstract: | In this study, the hetero-structure of MgCo2O4 nanowires (MCO-NWs) and microcubes (MCO-MCs) on the skeleton of nickel foam (NF) was realized through a simple hydrothermal method and subsequent annealing treatment, and then served as a binder-free cathode for assembly of high-performance hybrid supercapacitor (HSC). Such synthetic methodology avoided the traditional usage of conductive and binder reagents for the electrode fabrication. The electrochemical tests indicated its battery-type characteristics, and the MCO-NWs@NF exhibited a huge specific capacity (Cs) of 389.0 C g?1 as well as 86.2% capacity retention when the current density boosted from 1 to 10 A g?1. The assembled HSC with activated carbon (AC) as anode further demonstrated the advantages of this electrode material. After 5000 cycles at 6 A g?1, the MCO-NWs@NF//AC HSC showed good long-term cycling stability without any decay in capacitance, and could deliver an energy density (Ed) of 37.9 W h kg?1 at the power density (Pd) of 958.1 W kg?1, higher than the 30.4 W h kg?1 of MCs-based HSC. These impressive results regarding electrochemical performance suggest that MCO-NWs@NF may be a promising candidate to serve as a battery-type material in electrochemical energy storage applications such as HSCs, batteries, and so on. |
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Keywords: | Supercapacitors Binder-free electrode Hydrothermal synthesis |
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