LIQUID-LIQUID EXTRACTION STUDIES OF METAL IONS WITH DIAZACROWN AND STRUCTURE ANALOGOUS OPEN-CHAIN COMPOUNOS

1,10-diaze [8]crown-6, their N,N'-dibutyl- and dioctyl-substituted derivatives and the structure analogous open-chein tetreoxedieza slkanee have been synthesized in order to examine the extraction properties for Na⁺, K⁺, Sr²⁺ and Hg²⁺. It wes found, that the extraction of strontium, potassium and sodium picratee with azacrown compounds ie much higher than that with open-chein oxaaze alkanes. 1,10-diaze [18] erown-6 has a good selectivity for the extraction of Sr²⁺ over K⁺ and Na in alkaline solution. In the case of Sr²⁺ the diffarencea between tha various azacrown compounds are email, whereea in the caee of K⁺ and Na the substituted derivativee are better extractante. Theserssulte correspond qualitativsly with tha order of stebility conetantB in protic solvsnts. The extrectebility of N,N'-dioctyl-l, 10-dieze[18]crown-6 for HgCl₂ is very high. Contrerv to the order of stability conetants the uneubetituted conpound do not extract mercury under the choeen experimental condition*. The extraction power of open-chain conpounde ie aleo high and strong Influenced by the alkyl eubatltuente at the nitrogen donor stons,