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Recent anode advances in solid oxide fuel cells
Authors:Chunwen Sun  Ulrich Stimming
Affiliation:1. Department of Physics E19, Technische Universität München, James-Franck Strasse 1, D-85748 Garching, Germany;2. Bavarian Center for Applied Energy Research (ZAE Bayern), Division 1, Walther-Meiβner Strasse 6, D-85748 Garching, Germany
Abstract:Solid oxide fuel cells (SOFCs) are electrochemical reactors that can directly convert the chemical energy of a fuel gas into electrical energy with high efficiency and in an environment-friendly way. The recent trends in the research of solid oxide fuel cells concern the use of available hydrocarbon fuels, such as natural gas. The most commonly used anode material Ni/YSZ cermet exhibits some disadvantages when hydrocarbons were used as fuels. Thus it is necessary to develop alternative anode materials which display mixed conductivity under fuel conditions. This article reviews the recent developments of anode in SOFCs with principal emphasis on the material aspects. In addition, the mechanism and kinetics of fuel oxidation reactions are also addressed. Various processes used for the cost-effective fabrication of anode have also been summarized. Finally, this review will be concluded with personal perspectives on the future research directions of this area.
Keywords:Solid oxide fuel cells   Anode materials   Microstructure   Reaction mechanism   Kinetics
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