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七氟丙烷对磷酸铁锂储能电池的灭火效果
引用本文:张坚,李建勇,张明杰,田艳红,韩慧,杨凯,迟鸣声. 七氟丙烷对磷酸铁锂储能电池的灭火效果[J]. 消防科学与技术, 2020, 39(8): 1168-1181
作者姓名:张坚  李建勇  张明杰  田艳红  韩慧  杨凯  迟鸣声
作者单位:1. 北京化工大学材料科学与工程学院,北京100029;2. 中广核(上海)新能源有限公司,上海200241;3. 中国电力科学研究院有限公司新能源与储能运行控制国家重点实验室,北京100192
基金项目:中广核新能源上海分公司科技项目“储能系统锂电池热失效性能研究”(DGB11202000657)
摘    要:以七氟丙烷灭火剂为灭火介质,研究其在不同喷射方式下对磷酸铁锂储能电池火灾的灭火效果。研究发现:不同喷射方式均可在8 s 内扑灭明火,但灭火效果存在一定差异。七氟丙烷垂直喷射时,扑灭明火仅用2 s,且瞬时降温速率最大可达43 ℃/s。抑制复燃时间长,持续升温时间以及持续冒烟时间短。在喷射方式的选择上应尽量保证灭火剂喷口能够覆盖在电池正上方,这样能够最大化发挥七氟丙烷的灭火效果。

关 键 词:磷酸铁锂电池  七氟丙烷  灭火方式  抑制复燃  

Fire extinguishing effect of heptafluoropropane on fire of lithium iron phosphate energy storage batteries
ZHANG Jian,LI Jian-yong,ZHANG Ming-jie,TIAN Yan-hong,HAN Hui,YANG Kai,CHI Ming-sheng. Fire extinguishing effect of heptafluoropropane on fire of lithium iron phosphate energy storage batteries[J]. Fire Science and Technology, 2020, 39(8): 1168-1181
Authors:ZHANG Jian  LI Jian-yong  ZHANG Ming-jie  TIAN Yan-hong  HAN Hui  YANG Kai  CHI Ming-sheng
Affiliation:1.College of Materials and Engineering, Beijing University of Chemical Technology,Beijing 100029, China; 2.CGNPC (Shanghai) New Energy Co., Ltd., Shanghai 200241, China; 3.State Key Laboratory of Operation and Control of Renewable Energy & Storage Systems, China Electric Power Research Institute,Beijing 100192, China
Abstract:Heptafluoropropane was used as extinguishing agent to research the fire extinguishing effect on fire of lithium iron phosphate energy storage battery under different injection modes. It is found that all modes of injection can extinguish open flames within 8s, but the extinguishing effect is different. When heptafluoropropane is sprayed vertically, it only takes 2 s to extinguish open flames, and the instantaneous cooling rate can reach 43 ℃/s at most. The suppression time of reburning is long, the duration of temperature rising and the duration of smoking are short. The extinguishing agent nozzle should coverup of the batterydirectly to maximize the extinguishing effect of heptafluoropropane of injection mode.
Keywords:Lithium iron phosphate battery,heptafluoropropane  fire extinguishing method,suppression of reburning,
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