| 尾式谷氨酸卟啉及其金属配合物的合成 |
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| 引用本文： | 张丽君,杨富兴.尾式谷氨酸卟啉及其金属配合物的合成[J].河北化工,2002(4):26-27. |
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| 作者姓名： | 张丽君 杨富兴 |
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| 作者单位： | 河北师范大学化学系 河北石家庄050016
(张丽君)，河北师范大学化学系 河北石家庄050016(杨富兴) |
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| 摘 要： | 合成了5－对－N－谷氨酸丁氧基）苯基]－10，15，20－三（对氯苯基）卟啉（H2L）及其配合物MLCl(M=Co，Fe,Mn)，并对它们进行了元素分析，UV－cis，荧光光谱，IR和^1H NMR等结构表征。催化实验发现，除配体外，3种配合物在分子氧氧化苯甲醛的反应中具有催化作用。
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| 关 键 词： | 尾式谷氨酸卟啉 金属配合物 合成 催化 结构表征 |
Synthesis of The Tailed Glutamin Acid Tetraphenyl-Porphyin And Its Compelexes |
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| ZHANG Li-jun,YANG Fu-xing.Synthesis of The Tailed Glutamin Acid Tetraphenyl-Porphyin And Its Compelexes[J].Hebei Chemical Engineering and Industry,2002(4):26-27. |
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| Authors: | ZHANG Li-jun YANG Fu-xing |
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| Abstract: | Meso-5-p-N-glutamic acid butoxyl)phenyl]-10,15,20-tri(p-chlorophenyl)porphyrin(H2L)and its complexes MLCl(M=Co,Fe,Mn)were synthesized and were characterized by 1HNMR,IR,UV-vis and fluorescence spcetra.The oxidation of aromatie aldehyes with O2 has been investigated in the presence of complexes.It was observed the complexes MLCl can all catalyze the oxidation aromatic aldehydes,while H2L is inactive,CoL is the better catalyst compared with other tailed amino acid porphyrins in the same condition. |
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| Keywords: | tailed-porphyrin glutamic acid synthesis complexe catalyte |
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