Inverse analyses of diffusion processes in type 13X zeolite particles |
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Affiliation: | 1. The Key Laboratory of Solid Waste Treatment and Resource Recycle, Ministry of Education, Southwest University of Science and Technology, Mianyang, Sichuan 621010, PR China;2. The School of Resource and Environment, Southwest University, Chongqing 400715, PR China;3. School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, 2 George Street, GPO Box 2434, Brisbane, Queensland 4001, Australia |
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Abstract: | To determine effective surface self-diffusion coefficients of CO2 within type 13X zeolite particles, at various temperatures (25–70 °C), inverse analyses of observed CO2-uptake curves were successfully performed. The obtained effective surface self-diffusion coefficients increase with both the amount adsorbed and the temperature and ranged from 7.8 × 10?10 to 1.95 × 10?9 m2/s under the present experimental conditions. |
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