| 钠盐处理钯炭催化反式-4-丙基环己基苯酚加氢制备4-(4-丙基环己基)环己酮的研究 |
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| 引用本文： | 汪义坤,王纬东,王小伟,袁江波.钠盐处理钯炭催化反式-4-丙基环己基苯酚加氢制备4-(4-丙基环己基)环己酮的研究[J].化学世界,2010,51(7). |
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| 作者姓名： | 汪义坤 王纬东 王小伟 袁江波 |
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| 作者单位： | 渭南海泰新塑电子材料有限责任公司,陕西,渭南714000 |
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| 摘 要： | 以EDTA二钠盐、硝酸钠混合处理钯炭,钠盐处理后的钯炭对4-(4-丙基环己基)苯酚(3PCO)加氢制备4-(4-丙基环己基)环己酮(3 HHK)有很高的选择性,用质量比5%的EDTA二钠盐、2%硝酸钠混合处理钯炭,在高温高压下加氢,3 HHK的选择性达到60%以上。用GC检测加氢产品。
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| 关 键 词： | EDTA二钠盐 钯炭 反式-4-丙基环己基苯酚(3PCO) 4-(4-丙基环己基)环己酮(3HHK) 高温高压 |
Hydrogenation of 4-(trans-4-Propylcyclohexyl)phenol to 4-(4-propylcyclohexyl) cyclohexanone Catalyzed by Palladium/carbon Treated with Sodium Salt |
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| WANG Yi-kun,WANG Wei-dong,WANG Xiao-wei,YUAN Jiang-bo.Hydrogenation of 4-(trans-4-Propylcyclohexyl)phenol to 4-(4-propylcyclohexyl) cyclohexanone Catalyzed by Palladium/carbon Treated with Sodium Salt[J].Chemical World,2010,51(7). |
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| Authors: | WANG Yi-kun WANG Wei-dong WANG Xiao-wei YUAN Jiang-bo |
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| Abstract: | Palladium/carbon catalyst treated with 5% disodium EDTA salt mixed with 2% sodium nitrate was used in the hydrogenation of propyl cyclohexyl-phenol to 4-propyldicyclohexanone.The reaction occured at high temperature and high pressure,and the selectivity reached 60%.The product was analyzed by GC. |
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| Keywords: | disodium EDTA salt palladium/carbon 4-(trans-4-propylcyclohexyl)phenol l 4-(4-propylcyclohexyl)cyclohexanone high temperature and high pressure |
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