| 电解质溶液热力学性质的研究进展 |
| |
| 引用本文： | 苑宏刚,周立岱,张震斌. 电解质溶液热力学性质的研究进展[J]. 化学工业与工程技术, 2006, 27(5): 34-38 |
| |
| 作者姓名： | 苑宏刚 周立岱 张震斌 |
| |
| 作者单位： | 辽宁工学院,辽宁,锦州,121001 |
| |
| 摘 要： | 从电解质溶液的经典理论、半经验模型和统计力学3方面综述了电解质溶液热力学性质的研究进展,并对各种理论和模型在理论与实践方面的局限性作了相关评述。从分子、离子角度对电解质溶液的热力学性质进行研究比较,探讨了其宏观热力学性质与微观结构的相关性。展望了电解质溶液热力学理论近期研究的热点和未来的发展方向。
|
| 关 键 词： | 电解质溶液 热力学性质 离子 活度系数 模型 |
| 文章编号： | 1006-7906（2006）05-0034-05 |
| 收稿时间： | 2006-04-20 |
| 修稿时间： | 2006-04-20 |
Research advance of thermodynamic properties for electrolyte solutions |
| |
| Yuan Honggang,Zhou Lidai,Zhang Zhenbin. Research advance of thermodynamic properties for electrolyte solutions[J]. Journal of Chemical Industry & Engineering, 2006, 27(5): 34-38 |
| |
| Authors: | Yuan Honggang Zhou Lidai Zhang Zhenbin |
| |
| Abstract: | The research advance of thermodynamic properties for electrolyte solutions is summarized from three aspects,i.e.,tradi- tional solution theory,semi-empirical model and statistical mechan- ics.The limitations of every theory and model in theory and practice are appraised.The relativity about macroscopic thermodynamic properties and microstructure of electrolyte solutions is discussed af- ter thermodynamic properties are compared from molecule and ion aspects.The recent research hotspot of thermodynamic theory and future development direction are predicted. |
| |
| Keywords: | Electrolyte solution Thermodynamic properties Ion Activity coefficient Model |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
