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Stable organic photovoltaic with PEDOT:PSS and MoOX mixture anode interfacial layer without encapsulation
Affiliation:1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, PR China;2. Department of Electrical Engineering and Computer Sciences, College of Engineering, South Dakota State University, Brookings, South Dakota 57007, USA;3. Department of Materials Science and Engineering, Erik Jonsson School of Engineering and Computer Science, University of Texas at Dallas, Richardson, TX 75083, USA;4. Department of Synthetic Chemistry and Biological Chemistry, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510, Japan;1. Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu 300, Taiwan;2. Department of Electronics Engineering, National Chiao Tung University, Hsinchu 300, Taiwan;1. School of Physical Science and Technology, Southwest University, Chongqing 400715, PR China;2. Material Science and Engineering, Arizona State University, 7700 S. River Parkway, Tempe, AZ 85284, United States;1. Institute of Materials for Electronics and Energy Technology (i-MEET), Friedrich-Alexander Universität Erlangen-Nürnberg, Martensstrasse 7, 91058 Erlangen, Germany;2. Bavarian Center for Applied Energy Research (ZAE Bayern), Haberstraße 2a, 91058 Erlangen, Germany;3. Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich-Alexander Universität Erlangen-Nürnberg, Germany;4. Center of Nanoanalysis and Electron Microscopy (CENEM), Friedrich-Alexander Universität Erlangen-Nürnberg, Cauerstraße 6, 91058 Erlangen, Germany
Abstract:Herein, we report about an efficient and stable organic photovoltaic that uses a poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate) (PEDOT:PSS) and molybdenum oxide (MoOX) mixture for the anode interfacial layer, and that can reach 4.43% power conversion efficiency (PCE) under AM1.5 conditions. Utilizing PEDOT:PSS:MoOX (1:1), the shelf lifetime of poly(3-hexylthiophene) (P3HT), and indene-C60 bisadduct (ICBA)-based solar cells without encapsulation, can be realized with only a 25% deterioration after 672 h of storage in air. Furthermore, we compare the photovoltaic performance of the P3HT:ICBA-based organic photovoltaic with PEDOT:PSS, and PEDOT:PSS:MoOX, in which PEDOT:PSS:MoOX has outperformed the others. In addition, the water vapor transmission rate of PEDOT:PSS:MoOX is 0.17 gm/(m2 day), which is much less than that of PEDOT:PSS.
Keywords:Organic photovoltaic  PEDOT:PSS  Metal oxide  Stable
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