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Solvent Selection for Extractive Distillation by the Universal Quasichemical Functional Group Activity Coefficient(UNIFAC) Group Contribution Method
引用本文:崔现宝,翟亚锐,杨志才,冯天扬,张缨. Solvent Selection for Extractive Distillation by the Universal Quasichemical Functional Group Activity Coefficient(UNIFAC) Group Contribution Method[J]. 中国化学工程学报, 2004, 0(6)
作者姓名:崔现宝  翟亚锐  杨志才  冯天扬  张缨
作者单位:State Key Laboratory of Chemical Engineering School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China,Library of Tianjin University Tianjin 300072,China,State Key Laboratory of Chemical Engineering School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China,State Key Laboratory of Chemical Engineering School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China,State Key Laboratory of Chemical Engineering School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China
摘    要:
A method to select solvent for extractive distillation is proposed by UNIFAC group contribution. Solvent selectivity can be divided into two parts: the partial combinatorial solvent selectivity and the partial residual solvent selectivity. The properties of partial combinatorial and residual solvent selectivity are demonstrated. In most cases, the partial residual solvent selectivity is predominant. The candidate groups of solvent can be selected by group interaction parameter using UNIFAC group interaction parameter table as a guide.


Solvent Selection for Extractive Distillation by the Universal Quasichemical Functional Group Activity Coefficient(UNIFAC) Group Contribution Method
CUI Xianbao,ZHAI Yarui,YANG Zhicai FENG Tianyang and ZHANG YingState Key Laboratory of Chemical Engineering,School of Chemical Engineering and Technology,Tianjin University,Tianjin ,China Library of Tianjin University,Tianjin ,China. Solvent Selection for Extractive Distillation by the Universal Quasichemical Functional Group Activity Coefficient(UNIFAC) Group Contribution Method[J]. Chinese Journal of Chemical Engineering, 2004, 0(6)
Authors:CUI Xianbao  ZHAI Yarui  YANG Zhicai FENG Tianyang  ZHANG YingState Key Laboratory of Chemical Engineering  School of Chemical Engineering  Technology  Tianjin University  Tianjin   China Library of Tianjin University  Tianjin   China
Affiliation:CUI Xianbao,ZHAI Yarui,YANG Zhicai FENG Tianyang and ZHANG YingState Key Laboratory of Chemical Engineering,School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China Library of Tianjin University,Tianjin 300072,China
Abstract:
A method to select solvent for extractive distillation is proposed by UNIFAC group contribution. Solvent selectivity can be divided into two parts: the partial combinatorial solvent selectivity and the partial residual solvent selectivity. The properties of partial combinatorial and residual solvent selectivity are demonstrated. In most cases, the partial residual solvent selectivity is predominant. The candidate groups of solvent can be selected by group interaction parameter using UNIFAC group interaction parameter table as a guide.
Keywords:solvent selection   solvent selectivity   UNIFAC   group contribution   extractive distillation
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