Electrochemical kinetic study of the Fe3+Fe2+ system in oxalate medium |
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| Authors: | V. Lopez M.J. Peña |
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| Affiliation: | Departamento de Electroquímica, Departamento de Investigaciones Químicas, Centro Coordinado C.S.I.C., Universidad Autónoma, Canto Blanco, Madrid 34, Spain |
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| Abstract: | The overall processes were determined for the reduction of Fe3+ to Fe2+, in an oxalate medium and at oxalate concentrations of less than 0.5M. The coordination numbers of the oxidized and reduced species were calculated, together with the number of intervening protons that depend on the oxalate concentration and the pH.In addition, the species that reduces at the electrode is determined, together with the intensity equations for each process. |
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| Keywords: | To whom correspondence should be addressed. |
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