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Unique photoelectrochemical behavior of TiO2 nanorods wrapped with novel titanium Oxy-Nitride (TiOxNy) nanoparticles
Authors:Maheswari Arunachalam  Gun Yun  Kwang-Soon Ahn  Won-Seon Seo  Dae Soo Jung  Soon Hyung Kang
Affiliation:1. Department of Chemistry, Chonnam National University, Gwangju, 500-757, South Korea;2. Department of Chemistry Education and Optoelectronic Convergence Research Center, Chonnam National University, Gwangju, 500-757, South Korea;3. School of Chemical Engineering, Yeungnam University, Gyeongsan, 712-749, South Korea;4. Energy & Environmental Division, Korea Institute of Ceramic Engineering & Technology (KICET), 101 Soho-ro, Jinju-si, Gyeongsangnam-do, 52581, Republic of Korea
Abstract:In this work, we developed novel titanium oxynitride (TiOxNy) nanoparticles with diameter of 25 ± 2 nm and crystalline size of ~15 nm on hydrothermally grown one-dimensional (1D) TiO2 nanorod (TNR) arrays. Herein, the TiOxNy nanoparticles were synthesized by facile nitridation using TiO2 powder at 100% NH3 gas atmosphere. Titanium oxynitride composed of potentially energetic metal-nitrogen bonds (Ti/>N), compared to the weaker Ti<img style=
Keywords:Photoelectrochemical water splitting  Heterojunction  Charge separation efficiency
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