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炭基锌锰铜煤气脱硫剂的硫化行为研究
引用本文:靳庆麦,郑仙荣,王海堂,廖俊杰,常丽萍.炭基锌锰铜煤气脱硫剂的硫化行为研究[J].现代化工,2009,29(Z1).
作者姓名:靳庆麦  郑仙荣  王海堂  廖俊杰  常丽萍
作者单位:太原理工大学煤科学与技术教育部和山西省重点实验室,山西,太原,030024
摘    要:对锌、锰、铜摹单金属和复合金属氧化物脱硫剂的脱硫性能进行了讨论,并对炭材料作为脱硫剂和载体的研究现状进行了分析,同时对活化半焦作为脱硫剂载体的可行性进行了探讨.认为复合金属氧化物脱硫剂能够发挥单氧化物的优势,并克服其不足.将复合金属氧化物负载于炭材料上,可提高金属氧化物活性组分的利用率,改善脱硫剂的硫化性能,同时降低脱硫剂成本,使炭基锌锰铜复合金属氧化物煤气脱硫剂具有广阔的应用前景.

关 键 词:炭基材料  锌锰铜  脱硫剂  煤气净化

Study on sulfidation performance of carbon-based Zn/Mn/Cu desulfurizer in coal gas
JIN Qing-mai,ZHENG Xian-rong,WANG Hai-tang,LIAO Jun-jie,CHANG Li-ping.Study on sulfidation performance of carbon-based Zn/Mn/Cu desulfurizer in coal gas[J].Modern Chemical Industry,2009,29(Z1).
Authors:JIN Qing-mai  ZHENG Xian-rong  WANG Hai-tang  LIAO Jun-jie  CHANG Li-ping
Abstract:The desulfurization performances of single and mixed oxides sorbents with Zn,Mn,Cu are systematically reviewed.The properties of carbon-based materials used as desulfurizers and carriers are also discussed.In addition,the feasibility of activated semi-coke as carrier is confrmed.It is found that carbon-based metal-oxide desulfufizers can hold the advantages of each single metal oxide and eliminate their shortcomings.Zn-Mn-Cu mixed metal oxides supported on the carbonbased materials have extensive application prospect in removing sulfur from hot coal gas.
Keywords:carbon-based  Zn/Mn/Cu  desulfurizer  gas purification
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