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Pd-, Ni-, Fe-, and Co-Catalyzed Cross-Couplings Using Functionalized Zn-, Mg-, Fe-, and In-Organometallics
Authors:Paul Knochel  Tobias Thaler  Coura Diene
Affiliation:Department of Chemistry, Ludwig-Maximilians-University, Butenandtstrasse 5-13, 81377 Munich, Germany phone: +49 (0)89 2180 77681 fax: +49 (0)89 2180 77680
Abstract:The development of new methods for preparing polyfunctional organometallics has made a broad range of such reagents available for various transition metal-catalyzed cross-couplings. An overview of the most general preparation methods will be presented. Applications to practical cross-coupling procedures will be covered, emphasizing the functional group compatibility and the reaction scope.
Keywords:cross-coupling  Grignard reagents  iron catalysis  nickel  palladium
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