R-Curve Behavior and Crack-Closure Stresses in Barium Titanate and (Mg,Y)-PSZ Ceramics

R -curves, process zones, and shielding stresses of barium titanate (BaTiO₃) and partially stabilized zirconia (PSZ) have been studied using compact-tension (CT) specimens. BaTiO₃ and PSZ exhibited pronounced R -curves that rose over similar crack lengths and showed steady-state toughnesses of 0.7 and 6.4 MPa·m^1/2, respectively. Both steady-state toughnesses were ～80% larger than the initial fracture toughnesses. Ferroelastic domain switching was the main toughening mechanism in BaTiO₃, whereas, in PSZ, transformation toughening was the main toughening mechanism. The crack process zone and crack-opening-displacement (COD) profile of each material was studied in detail using atomic force microscopy. Crack-closure-stress distributions were extracted from the COD profiles, using weight-function methods. The resulting stress profiles indicated that compressive residual stresses of 40 MPa in BaTiO₃ and 400 MPa in PSZ acted in a limited region behind the crack tip. In the PSZ, crack bridging seemed to be a competing mechanism to transformation toughening.