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Behaviors of Rare Earths during Fluid-Rock Interaction and Its Significance of Geochemistry
Authors:LING Qi cong  LIU Cong qiang
Abstract:Rare earths in ores, altered and unaltered sericite phyllite, altered and unaltered dacite porphyry were determined in order to examine behaviors of rare earths in hydrothermal alteration associating with ore forming processes of Yinshan deposit. It is not sufficient to show the mobility only by the absolute abundance of trace elements changes before and after alteration. This can simply result from dilution or concentration if other elements are added to or removed from the rock. As shown by that in Yinshan deposit, less than 20% of the increment of RE was caused by the "condensed" of leaching some of major elements (e.g. Si, Na) from the rock. The principal factor which should be responsible for the higher contents of RE in altered rock is the addition of RE into the rock by hydrothermal fluids. Eu is selectively leached from the altered sericite phyllite by a mild acidity and reducing fluid which is characterized by much lower LRE/HRE ratio and a large positive Eu anomaly. A major effect on the RE patterns is the tendency to develop relatively flatter chondrite normalized patterns. The RE characteristics may be used to distinguish between small and large ore bodies at a later stage of exploration.
Keywords:rare earths  mobilities of rare earths  fluid  rock interaction  epimetamorphic phyllite  Yinshan deposit
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