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| 环氧化合物开环聚合催化剂的研究进展 | |
| 引用本文： | 陈华,朱新宝,王康芳,郝静琳. 环氧化合物开环聚合催化剂的研究进展[J]. 化学工业与工程技术, 2008, 29(2): 40-45 |
| 作者姓名： | 陈华 朱新宝 王康芳 郝静琳 |
| 作者单位： | 1. 南京林业大学,化工学院,江苏,南京,210037 2. 扬州晨化集团,江苏,宝应,225803 |
| 摘 要： | 介绍了环氧化物开环聚合用催化剂及聚合机理，并对阳离子、阴离子、配位开环聚合方法的应用及各自的优缺点进行了探讨。介绍了各种催化体系的工艺进展，指出生物酶和磷腈类催化剂具有好的研究前景。 |
| 关 键 词： | 环氧化物 开环聚合 催化剂 |
Research progress on ring-opening polymerization catalyst of epoxide |
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| Chen Hua,Zhu Xinbao,Wang Kangfang,Hao Jinglin. Research progress on ring-opening polymerization catalyst of epoxide[J]. Journal of Chemical Industry & Engineering, 2008, 29(2): 40-45 | |
| Authors: | Chen Hua Zhu Xinbao Wang Kangfang Hao Jinglin |
| Affiliation: | Chen Hua , Zhu Xinbao , Wang Kangfang , Hao Jinglin (1. Department of Chemistry, Nanjing Forestry University, Nanjing 210037, China; 2. Yangzhou Chenhua Technology Group, Baoying 225803,China) |
| Abstract: | The catalyst and mechanism of epoxide ring-opening polymerization is introduced.The application and their advantages and disadvantages of the cationic,the anionic,and the coordination ring-opening polymerization method are discussed.The process progress of a variety of catalytic system is introduced.The enzyme and phosphorus nitriles catalyst with good prospects for research are pointed out. |
| Keywords: | Epoxide Ring-opening polymerization Catalyst |
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