| 纳米ATO在有机单体介质中的表面改性及分散研究 |
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| 引用本文： | 张贵军,陈中华,曾幸荣,余飞.纳米ATO在有机单体介质中的表面改性及分散研究[J].功能材料,2009,40(11). |
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| 作者姓名： | 张贵军 陈中华 曾幸荣 余飞 |
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| 作者单位： | 1. 华南理工大学,材料科学与工程学院,广东,广州,510640
2. 华南理工大学,材料科学与工程学院,广东,广州,510640;广东省特种涂料工程技术研究开发中心,广东,广州,510520 |
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| 基金项目： | 国家自然科学基金，广东省科技攻关项目，广州市科技攻关重大项目 |
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| 摘 要： | 选用了多种改性剂,用超声波为分散手段,将纳米ATO粉体在有机单体介质中进行表面改性和分散,研究了改性剂种类、改性剂用量、改性时间、超声波输出功率和超声波处理时间等对纳米ATO-单体分散液稳定性的影响,探讨了纳米ATO表面改性机理.结果表明,硅烷偶联剂KH-570是纳米ATO的最佳改性剂,当其用量为纳米ATO的15%(质量分数),改性时间为24h,超声波输出功率为90%,超声波处理时间为12min时,纳米ATO-单体分散液具有最佳的分散稳定性.KH-570主要通过在纳米ATO表面水解产生硅羟基的自缩合,形成包覆改性.
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| 关 键 词： | 纳米ATO 有机单体 表面改性 分散 硅烷偶联剂 |
Surface modification and dispersion of nanometer-sized antimony doped tin oxide (ATO) particles in organic monomer medium |
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| ZHANG Gui-jun,CHEN Zhong-hua,ZENG Xing-rong,YU Fei.Surface modification and dispersion of nanometer-sized antimony doped tin oxide (ATO) particles in organic monomer medium[J].Journal of Functional Materials,2009,40(11). |
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| Authors: | ZHANG Gui-jun CHEN Zhong-hua ZENG Xing-rong YU Fei |
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| Affiliation: | ZHANG Gui-jun1,CHEN Zhong-hua1,2,ZENG Xing-rong1,YU Fei1(1.School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,China,2.Guangdong Special Coating Technical Research and Developing Center,Guangzhou 510520,China) |
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| Abstract: | Nanometer-sized antimony doped tin oxide (ATO) particles have been surface-modified and dispersed in organic monomer medium with different kinds of modifiers by using ultrasonic.The effects of modifier type,the amount of modifier,modification time,ultrasonic power output,and ultrasonic time on the dispersion stability of nanometer-sized ATO-monomer dispersion were studied and the surface modification mechanism was discussed.The results show that the nanometer-sized ATO-monomer dispersion with the optimal di... |
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| Keywords: | nanometer-sized ATO organic monomer surface modification dispersion silane coupling agent |
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