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One-Step Oxidation of Benzene to Phenol over Cu/Ti/HZSM-5 Catalysts
Authors:Yuichi Ichihashi  Yo-hei Kamizaki  Naoya Terai  Keita Taniya  Shigeru Tsuruya  Satoru Nishiyama
Affiliation:1. Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe, 657-8501, Japan
Abstract:The gas-phase catalytic oxidation of benzene over copper supported on HZSM-5 added with titanium (Cu/Ti/HZSM-5) was carried out by using molecular oxygen as an oxidant. Phenol was effectively produced by the titanium addition to Cu/HZSM-5. The titanium addition to Cu/HZSM-5 induces the easy reduction of Cu2+ species to Cu+ species in the catalysts, and the produced Cu+ species seems to produce the phenol effectively.
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