One-Step Oxidation of Benzene to Phenol over Cu/Ti/HZSM-5 Catalysts |
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Authors: | Yuichi Ichihashi Yo-hei Kamizaki Naoya Terai Keita Taniya Shigeru Tsuruya Satoru Nishiyama |
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Affiliation: | 1. Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe, 657-8501, Japan
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Abstract: | The gas-phase catalytic oxidation of benzene over copper supported on HZSM-5 added with titanium (Cu/Ti/HZSM-5) was carried out by using molecular oxygen as an oxidant. Phenol was effectively produced by the titanium addition to Cu/HZSM-5. The titanium addition to Cu/HZSM-5 induces the easy reduction of Cu2+ species to Cu+ species in the catalysts, and the produced Cu+ species seems to produce the phenol effectively. |
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