| 新型salamo衍生物苦味酸铜(Ⅱ)配合物的合成与表征 |
| |
| 引用本文： | 冯建华. 新型salamo衍生物苦味酸铜(Ⅱ)配合物的合成与表征[J]. 应用化工, 2008, 37(6) |
| |
| 作者姓名： | 冯建华 |
| |
| 作者单位： | 滁州学院,化学与生命科学系,安徽,滁州,239012 |
| |
| 摘 要： | 以丙酮为溶剂,1,3-二胺氧丙烷双缩邻香草醛(H2L)与苦味酸铜反应,制备了一种新型salamo衍生物苦味酸铜(Ⅱ)配合物,其结构经元素分析,1HNMR,IR,TG-DTA及UV表征。结果表明,新型salamo衍生物是一种四齿配体,配合物的可能结构式为[Cu4L2(pic)4(H2O)2].2CH3COCH3.2H2O。
|
| 关 键 词： | salamo衍生物 铜(Ⅱ)配合物 合成 表征 |
Synthesis and characterization of a novel Cu(II) picrate complex with salamo derivative |
| |
| FENG Jian-hua. Synthesis and characterization of a novel Cu(II) picrate complex with salamo derivative[J]. Applied chemical industry, 2008, 37(6) |
| |
| Authors: | FENG Jian-hua |
| |
| Abstract: | A novel Cu(II) picrate complex was prepared from copper(II) picrate and 6,6'-dimethoxy-2,2'-[(1,3-propylene)dioxybis(nitrilomethylidyne)]diphenol(H2L) in acetone solvent.The structure was characterized by elemental analysis,1H NMR,IR,TG-DTA and UV.The novel salamo derivative are a good tetradentate N2O2-donating ligand,and the formula of the complex was suggested as [Cu4L2(pic)4(H2O)2]·2CH3COCH3·2H2O. |
| |
| Keywords: | salamo derivatives Cu(II) complex synthesis characterization |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
