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Structural,electrical, dielectric and magnetic behavior of Gd1?xBixFe1?yZryO3 nanoparticles for advanced technological applications
Affiliation:1. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur ,63100, Pakistan;2. Department of Chemistry, University of Gujrat, Gujrat, Pakistan;3. Department of Physics, The Islamia University of Bahawalpur, Bahawalpur, 63100, Pakistan;4. Deanship of scientific research, College of Engineering, PO Box 800, King Saud University, Riyadh 11421, Saudi Arabia;1. Department of Physics, BahauddinZakariya University, Multan 60800, Pakistan;2. Department of Physics, GC University Faisalabad, 68000, Pakistan;3. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;4. Department of Physics, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;1. Department of Physics, Bahauddin Zakariya University, Multan 60800, Pakistan;2. Department of Physics, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;3. College of E & ME, National University of Science and Technology, Islamabad, Pakistan;4. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;1. Department of Physics, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;2. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;3. Department of Chemistry,University of Gujrat, Gujrat 50700, Pakistan;4. Department of Chemistry, The University of Sargodha, Sargodha 40100, Pakistan;1. Department of Physics, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;2. Center for Computational Materials Science, Department of Physics, University of Malakand, Chakdara, Dir (Lower) 18800, Pakistan;3. Department of Physics, COMSATS Institute of Information Technology, Lahore 54000, Pakistan;4. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;5. Department of Physics, Abbottabad University of Science & Technology, Abbottabad, Pakistan;1. Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;2. Department of Physics, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan;3. Department of Physics, Balochistan University of Information Technology, Engineering & Management Sciences, Quetta 87300, Pakistan;4. Department of Electrical Engineering, King Saud University, Riyadh 11421, Kingdom of Saudi Arabia;5. Sustainable Energy Technologies Center, College of Engineering, King Saud University, Riyadh 11421, Kingdom of Saudi Arabia
Abstract:Gd1?xBixFe1?yZryO3 nanoparticles were synthesized via micro-emulsion route with different molar concentrations of Bi+3 (x) and Zr+4 (y). The values of x and y were kept in the range 0.00, 0.15, 0.30, 0.45 and 0.60. The characterizations were done by the thermo-gravimetric analysis (TGA), X-ray Diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The average particle size was ~50 nm. The effect of Bi3+ and Zr4+ contents on electrical, dielectric and magnetic parameters were studied. The DC resistivity measurements showed at certain Bi3+ and Zr4+ contents, more than two fold increase in electrical resistivity from 68×108 Ω cm to 150×108 Ω cm. The magnetic measurements showed the paramagnetic nature of Gd1?xBixFe1?yZryO3 nanoparticles. The electrical and magnetic properties of these nanoparticles suggested that these materials are potential candidates for the fabrication of telecommunication and switching devices.
Keywords:C  Dielectric properties  C  Magnetic properties  D  Perovskites  Nanoparticles  Electrical resistivity
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