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碲镉汞体材料的显微Raman光谱
引用本文:黄晖,唐莹娟,许京军,张存洲,潘顺臣,张光寅.碲镉汞体材料的显微Raman光谱[J].红外技术,2002,24(5):37-41.
作者姓名:黄晖  唐莹娟  许京军  张存洲  潘顺臣  张光寅
作者单位:1. 昆明物理研究所,云南,昆明,650223;南开大学物理科学学院光子学中心,天津,300071
2. 昆明物理研究所,云南,昆明,650223
3. 南开大学物理科学学院光子学中心,天津,300071
摘    要:利用Raman显微镜测量了ACRT-Bridgman方法和Te溶剂方法生长的碲镉汞体材料的显微Raman光谱,在碲镉汞体材料的显微Raman光谱中识别出了碲镉汞的基本光学振动模,由此证明了碲镉汞按晶格振动的分类方法属于二模混晶;识别出了一个来源于类HgTe的TO1模 LO1模的二级Raman散射峰;观察到了碲镉汞体材料中两个新的Raman散射峰,分别位于662cm^-1和749cm^-1;观察到了碲镉汞基本光学振动模的TO1模与LO1模的Raman散射强度比的变化,指出该现象是由于Raman散射几何配置不同引起的。

关 键 词:碲镉汞晶体  显微Raman光谱  光学振动膜  Raman散射
文章编号:1001-8891(2002)05-0037-05
修稿时间:2002年5月31日

Micro-Raman Spectra of Hg1-xCdxTe Bulk Crystals
HUANG Hui ,TANG Ying juan ,XU Jing jun ,ZHANG Cun zhou ,PAN Shun chen ,ZHANG Guang yin.Micro-Raman Spectra of Hg1-xCdxTe Bulk Crystals[J].Infrared Technology,2002,24(5):37-41.
Authors:HUANG Hui    TANG Ying juan  XU Jing jun  ZHANG Cun zhou  PAN Shun chen  ZHANG Guang yin
Affiliation:HUANG Hui 1,2,TANG Ying juan 1,XU Jing jun 2,ZHANG Cun zhou 2,PAN Shun chen 1,ZHANG Guang yin 2
Abstract:The basic phonon vibrations in MCT were recognized in the micro Raman spectra of MCT bulk crystals: The HgTe like TO 1 and LO 1 phonon vibrational modes located at 121 cm -1 and 139 cm -1 , respectively. The CdTe like TO 2 and LO 2 phonon vibrational modes located nearby 154 cm -1 . A Raman shift at 260 cm -1 was proposed to belong to the two phonon mode TO 1+LO 1. Therefore we can confirm that MCT belongs to two mode mix crystal. Two new Raman peaks at 662 cm -1 and 749 cm -1 were observed in MCT bulk material. The intensity ratio of TO 1 and LO 1 in MCT was observed to be different which was explained in terms of the different Raman geometry arrangement.
Keywords:Hg  1-  x  Cd  x  Te crystal    micro  Raman spectra
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