Raman Mapping of the Indentation-Induced Densification of a Soda-Lime-Silicate Glass

Micro-Raman spectroscopy was used to map the Vickers indentation-induced densification on a window glass (soda-lime silicate glass), from the correlation between Raman spectrum and density. Both top surface and cross-section of the residual imprints were investigated. It is shown that the sample preparation needed for the investigation of the in-depth densification does not alter the results. The maximum densification ratio measured is about 3.8%, which is 60% of the maximum densification measured after a high-pressure hydrostatic loading. Within the experimental errors, densification maps are self-similar for the two indentation loads used 10 N and 20 N. A comparison with finite element results based on a constitutive model developed for silica is discussed.