Gas hydration of trans-1,2-dimethylcyclohexane with cooperative assistance of methane and cis-1,2-dimethylcyclohexane |
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| Authors: | Toshiyuki Nakamura |
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| Affiliation: | Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan |
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| Abstract: | It has been regarded that the limit of the largest cage occupancy for the structure-H hydrate is between the 1,2-dimethylcyclohexane stereo-isomers, because the cis-isomer is able to generate the structure-H hydrate in the presence of methane while the trans-isomer is not. In the present study, gas hydration of trans-1,2-dimethylcyclohexane in the presence of methane and cis-1,2-dimethylcyclohexane is found from stability boundaries for the structure-H hydrate system. |
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| Keywords: | Gas hydrate Structure-H Gases Phase equilibria Solid solutions Stability |
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