| 无三苯CR/SBS/MMA/BA自交联鞋用胶粘剂的研制 |
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| 引用本文： | 张东亮,唐为丰,杨怀.无三苯CR/SBS/MMA/BA自交联鞋用胶粘剂的研制[J].橡胶工业,2002,49(6):333-336. |
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| 作者姓名： | 张东亮 唐为丰 杨怀 |
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| 作者单位： | 江苏石油化工学院,化工系,江苏,常州,213016 |
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| 摘 要： | 采用复合引发剂 ,以N 羟甲基丙烯酰胺 (NAM )及丙烯酸 (AA)为功能单体 ,与CR、苯乙烯 丁二烯嵌段共聚物 (SBS)、甲基丙烯酸甲酯 (MMA)和丙烯酸丁酯 (BA)进行多元共混接枝共聚 ,再配以混合型增粘树脂 ,研制出不含苯、甲苯和二甲苯 (简称三苯 )自交联环保型鞋用胶粘剂。探讨了SBS用量、MMA/BA配比、功能单体NAM及AA用量对胶粘剂粘合性能的影响。结果表明 ,CR/SBS/MMA/BA/AA/NAM自交联型接枝胶粘剂对非极性鞋材的粘合性能明显优于CR/MMA/BA三元接枝胶和CR/SBS/MMA/BA四元接枝胶。
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| 关 键 词： | CR 苯乙烯丁二烯嵌段共聚物 N羟甲基丙烯酰胺 丙烯酸丁酯 自交联 鞋用胶粘剂 |
| 文章编号： | 1000-890X(2002)06-0333-04 |
| 修稿时间： | 2001年12月31 |
Preparation of aromatic hydrocarbon-free and self-crosslinking CR/SBS/MMA/BA adhesive for shoes |
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| ZHANG Dong-liang,TANG Wei-feng and YANG Huai.Preparation of aromatic hydrocarbon-free and self-crosslinking CR/SBS/MMA/BA adhesive for shoes[J].China Rubber Industry,2002,49(6):333-336. |
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| Authors: | ZHANG Dong-liang TANG Wei-feng and YANG Huai |
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| Affiliation: | Jiangsu Institute of Petrochemical Technology,Jiangsu Institute of Petrochemical Technology and Jiangsu Institute of Petrochemical Technology |
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| Abstract: | A polybasic graft copolymerization of acrylic acid (AA) and N (hydroxymethyl) acrylamide (NAM) as functional monomers with methyl methacrylate (MMA),butyl acrylate (BA) on CR and SBS was carried out in an aromatic hydrocarbon free solvent by using composite initiator.An aromatic hydrocarbon free solvent and self crosslinking adhesive for shoes was prepared with the above copolymer by adding a tackifying resin.The influence of the addition levels of SBS,NAM and AA,and the MMA/BA ratio on the adhesive properties was investigated.The results showed that the properties of the above said adhesive bonded to non polar shoe materials were much better than those of both CR/MMA/BA terbasic graft copolymer adhesive and CR/SBS/MMA/BA tetrabasic graft copolymer adhesive. |
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| Keywords: | CR SBS NMA BA self crosslinking adhesive for shoes |
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