Synthesis,properties, and practical application of hyperbranched polymers |
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Authors: | G. V. Korolev M. L. Bubnova |
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Affiliation: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia |
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Abstract: | The methods of synthesis of hyperbranched polymers are considered and systematized with main attention focused on such modern and promising procedures of crosslinking free-radical polymerization as living chain and intense chain transfer regimes. The synthetic approach to hyperbranched polymers via free-radical oxidative polymerization is the first to be put forth. The main problems concerning these polymers are formulated, and the recent advances in this field are generalized and elucidated. |
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