| DBSA参杂聚丙烯接枝苯乙烯磺酸聚苯胺抗静电剂的制备与应用 |
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| 引用本文： | 祖立武;张晓宇;王雅珍.DBSA参杂聚丙烯接枝苯乙烯磺酸聚苯胺抗静电剂的制备与应用[J].中国塑料,2011,25(6):92-96. |
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| 作者姓名： | 祖立武;张晓宇;王雅珍 |
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| 作者单位： | 齐齐哈尔大学材料学院 |
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| 摘 要： | 以聚丙烯 (PP) 为基体,聚苯胺（SPSS）为接枝物，十二烷基苯磺酸（DBSA）为掺杂剂，采用溶液接枝法制备了高分子永久型抗静电剂聚丙烯接枝苯乙烯磺酸聚苯胺 (PP g SPS PANI)。探讨了DBSA及引发剂用量对该高分子抗静电剂性能的影响，利用红外光谱对该高分子抗静电剂进行了表征，通过扫描电子显微镜分析了PP/ PP g SPS PANI共混物的断面。结果表明，PP g SPS PANI可使PP体积电阻率降低到1.0×1012 Ω·cm，且二者有很好的相容性。
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| 关 键 词： | 聚丙烯 抗静电剂 十二烷基苯磺酸 掺杂 聚苯胺 |
| 收稿时间： | 2011-3-9 |
Preparation and Application of DBSA-doped Polypropylene Grafted Styrene Sulfonic Acid-polyaniline Antistatic Agents |
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| ZU Liwu,ZHANG Xiaoyu,WANG Yazhen.Preparation and Application of DBSA-doped Polypropylene Grafted Styrene Sulfonic Acid-polyaniline Antistatic Agents[J].China Plastics,2011,25(6):92-96. |
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| Authors: | ZU Liwu ZHANG Xiaoyu WANG Yazhen |
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| Affiliation: | ZU Liwu,ZHANG Xiaoyu,WANG Yazhen(College of Materials Science and Engineering,Qiqihar University,Qiqihar 161006,China) |
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| Abstract: | A high molecular weight permanent antistatic agent was prepared by solution grafting polymer. That is polypropylene (PP) as matrix, polyaniline(SPSS) for the graft, dodecylbenzene sulfonic acid (DBSA) as dopant (PP g SPS PANI) polymer complex . Inquiries into the effect of DBSA and initiator dosage on properties of polymer antistatic agent were made. PP g SPS PANI were characterized by FTIR and the fracture surfaces of PP blends were tested by SEM. The volume resistivity of PP g SPS PANI/PP can reduce to 1012Ω·cm and PP g SPS PANI /PP has good compatibility. |
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| Keywords: | polypropylene antistatic agent dodecylbenzenesulfonate acid doping polyaniline |
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