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Response to Disselkamp: Direct peroxide/peroxide fuel cell as a novel type fuel cell
Authors:AE Sanli  Aylin Aytaç
Affiliation:a Gazi University, Engineering Faculty, Department of Chemical Engineering, Clean Energy Research Center (CERC), Ankara, Turkey
b Gazi University, Science Faculty, Department of Chemistry, Clean Energy Research Center (CERC), Ankara, Turkey
Abstract:Besides hydrogen peroxide is known as conventionally oxidizer, it is both a fuel and a source of ignition. Platinum is not suitable catalyst for oxidation and reduction of hydrogen peroxide, because it directly converts the hydrogen peroxide to oxygen gas. In this study, the oxidation mechanism of peroxide is investigated and a fuel cell operating with acidic peroxide as oxidant and basic peroxide as fuel is constructed. The peroxide oxidation reaction in novel alkaline direct peroxide/peroxide fuel cell (DPPFC), shown feasible here using less expensive carbon supported Nickel catalyst, makes the alkaline direct peroxide/peroxide fuel cell a potentially low cost technology compared to PEM fuel cell technology, which employs platinum catalysts. The power density of 3.75 mW cm−2 at a cell voltage of 0.55 V and a current density of 14 mA cm−2 was achieved in our fuel cell.
Keywords:Hydrogen peroxide  Fuel cell  Electroless deposition  Nickel electrode
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