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干喷湿纺法PAN基碳纤维表面处理的研究
引用本文:史家武,龚文照,祁嘉昕,景阳岗,裴育民,刘会敏,王刚,袁秋华,王茂章,刘朗,杨永岗.干喷湿纺法PAN基碳纤维表面处理的研究[J].山西化工,2012,32(6):9-11.
作者姓名:史家武  龚文照  祁嘉昕  景阳岗  裴育民  刘会敏  王刚  袁秋华  王茂章  刘朗  杨永岗
作者单位:1. 阳煤化工设计院,山西太原,030021
2. 阳煤化工设计院,山西太原030021 中国科学院炭材料重点实验室,中科院山西煤炭化学研究所,山西太原030001
3. 山西汾西重工有限责任公司,山西太原,030027
4. 阳煤集团太原化工新材料有限公司,山西太原,030021
5. 中国科学院炭材料重点实验室,中科院山西煤炭化学研究所,山西太原030001
摘    要:以碳酸氢铵为电解质,对干喷湿纺法PAN基碳纤维进行了连续表面处理。通过扫描电子显微镜(SEM)分析其微观结构,同时利用万能材料实验机研究碳纤维及其复合机理。结果表明,随着处理电流密度的增大,碳纤维抗拉强度呈降低趋势。电化学处理碳纤维,电流密度最佳范围应为43.6A·m-^2~54.4A·m^-2,且碳纤维表面官能团对提高复合材料的层间剪切强度起关键作用。

关 键 词:干喷湿纺法  PAN基碳纤维  表面处理  电化学  复合材料  层间剪切强度

The Surface Treatment Study of Dry-jet West-spinning PAN-based Carbon Fibers
SHI Jia-wu,GONG Wen-zhao,QI Jia-xin,JING Yang-gang,PEI Yu-min,LIU Hui-min,WANG Gang,YUAN Qiu-hua,WANG Mao-zhang,LIU Lang,YANG Yong-gang.The Surface Treatment Study of Dry-jet West-spinning PAN-based Carbon Fibers[J].Shanxi Chemical Industry,2012,32(6):9-11.
Authors:SHI Jia-wu  GONG Wen-zhao  QI Jia-xin  JING Yang-gang  PEI Yu-min  LIU Hui-min  WANG Gang  YUAN Qiu-hua  WANG Mao-zhang  LIU Lang  YANG Yong-gang
Affiliation:1.Chemical Design and Research Institute,Yangquan Coal Industry(Group)Co.,Ltd.,Taiyuan Shanxi 030021,China; 2.Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan Shanxi 030001,China; 3.Shanxi Fenxi Heavy Industry Co.,Ltd.,Taiyuan Shanxi 030027,China; 4.Taiyuan New Chemical Material Co.,Ltd,Yangquan Coal Industry(Group)Co.,Ltd.,Taiyuan Shanxi 030021,China)
Abstract:Used ammonium bicarbonate as electrolyte, dry-jet wet-spinning PAN-based carbon fibers were continuously surface modified by electrochemical method. Scanning electron microscope (SEM) was employed to investigate the micro-structure, while universal material testing machine was introduced to study the mechanical property and recombination mechanism of carbon fibers and composite ma- terials. The results shows that, with the increase of treated current density, the strength of extension of carbon fibers were gradually reduced. During the electrochemical treatment, the optimal range of current density were 43.6 A. m^-2 ± 54.4 A . m^-2, and the surface functional groups of carbon fibers played a key role in improving the II.SS of composite materials.
Keywords:dry-jet wet-spinning  PAN-based carbon fibers  surface treatment  composite materials  ILSS
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