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| Pd/C催化有机锡试剂和酰氯偶联反应的研究 | |
| 引用本文： | 吴春,李健,李葵. Pd/C催化有机锡试剂和酰氯偶联反应的研究[J]. 化学试剂, 2004, 26(6): 361-362,375 |
| 作者姓名： | 吴春 李健 李葵 |
| 作者单位： | 哈尔滨商业大学,化学中心,黑龙江,哈尔滨,150076;黑龙江省育达药业公司,黑龙江,哈尔滨,150076 |
| 基金项目： | 黑龙江省自然科学基金 (B0 1 0 5 )资助项目 |
| 摘 要： | 制备了活性炭负载钯催化剂，并用于有机锡试剂与取代肉桂酰氯交叉偶联合成查耳酮化合物的反应中。考察了催化剂的催化性能，用XPS方法对催化剂进行了表征，还对反应机理进行了研究和探讨。 |
| 关 键 词： | 活性炭负载钯 有机锡试剂 酰氯化合物 偶联反应 |
| 文章编号： | 0258-3283(2004)06-0361-02 |
Study on the coupling reaction of organotins and acid chlorides catalyzed by Pd/C |
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| WU Chun,LI Jian,LI Kui. Study on the coupling reaction of organotins and acid chlorides catalyzed by Pd/C[J]. Chemical Reagents, 2004, 26(6): 361-362,375 | |
| Authors: | WU Chun LI Jian LI Kui |
| Affiliation: | WU Chun *1,LI Jian 1,LI Kui 2 |
| Abstract: | The active carbon-supported palladium catalyst was prepared.The crosscoupling reaction of organotins with substituted cinnamoyl chlorides catalyzed by Pd/C for synthesis of chalcones was studied.The catalytic activity of Pd/C and the catalytic mechanism were also studied by XPS.The metallic Pd may be the active center for the coupling reaction. |
| Keywords: | active carbon-supported palladium organotin reagent acid chlorides coupling reaction |
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