| 新型L-苏氨酸尾式卟啉及其锌(II)配合物合成与表征 |
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| 引用本文： | 罗国添,马鸣华,刘九辉,林玉福.新型L-苏氨酸尾式卟啉及其锌(II)配合物合成与表征[J].化学世界,2003(6). |
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| 作者姓名： | 罗国添 马鸣华 刘九辉 林玉福 |
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| 作者单位： | 赣南师范学院化学系 江西赣州341000
(罗国添，刘九辉)，南方冶金学院图书馆 江西赣州341000
(马鸣华)，赣南师范学院化学系 江西赣州341000(林玉福) |
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| 基金项目： | 江西省教育厅科技计划资助课题 ( 2 0 0 2 0 110 ) |
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| 摘 要： | 为了探索手性金属卟啉配合物的结构与功能 ,用 L-苏氨酸和 5 -邻 -(2 -溴乙氧基 )苯基 ]-1 0 ,1 5 ,2 0 -三苯基卟啉为原料合成了一种新型 L-苏氨酸尾式卟啉及其锌 (II)配合物 ,通过元素分析、红外光谱、化学分析和质谱等对其进行了结构表征。测试并研究了它们在 40 0 0～ 40 0 cm- 1 范围内的傅里叶变换红外光谱 ,对主要谱带进行了经验归属
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| 关 键 词： | L-苏氨酸 尾式卟啉 锌(II)配合物 合成 表征 |
Synthesis and Characterization of L-Threonine Acid Tailed Porphyrin and Its Zhic(II) Complex |
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| LUO Guo tian ,MA Ming hua ,LIU Jiu hui ,LIN Yu fu.Synthesis and Characterization of L-Threonine Acid Tailed Porphyrin and Its Zhic(II) Complex[J].Chemical World,2003(6). |
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| Authors: | LUO Guo tian MA Ming hua LIU Jiu hui LIN Yu fu |
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| Affiliation: | LUO Guo tian 1,MA Ming hua 2,LIU Jiu hui 1,LIN Yu fu 1 |
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| Abstract: | In order to investigate the structures and function of chiral metalloporphyrin, a new L threonine acid tailed porphyrin and its zinc(II) complex were synthesized from L threonine acid and 5 o (bromoethoxyl)phenyl] 10,15,20 triphenyl prophyrin. FAB MS, IR, elemental analysis and chemical analysis methods were used to determine the structures of this porphyrin and its zinc complex. The FT IR spectra(4000~400 cm -1 ) of L threonine acid tailed porphyrin and its zinc complex were measured and the major bands were empirically assigned. |
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| Keywords: | L threonine tailed porphyrin zinc complex synthesis characterization |
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