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塔里木稠油及其组分结构参数的研究
引用本文:文萍,王晓丹,巩磊,崔敏,李传,郝海英,邓文安.塔里木稠油及其组分结构参数的研究[J].石油化工高等学校学报,2013(5):6-9.
作者姓名:文萍  王晓丹  巩磊  崔敏  李传  郝海英  邓文安
作者单位:[1]中国石油大学(华东)化学工程学院重质油国家重点实验室,山东青岛266555 [2]中国石油青海油田公司冷湖油田管理处,青海海西816300 [3]中国石油大港油田采油工艺研究院,天津300280 [4]中国石油大学(华东)理学院,山东青岛266555
基金项目:国家自然科学基金青年基金项目(21106186).
摘    要:以塔里木稠油1、塔里木稠油2、塔里木稠油3为原料,将3种稠油进行四组分的分离。通过元素分析、核磁共振等分析方法研究了3种稠油及其组分的基本性质,对稠油及其组分的平均结构参数进行分析计算。结果表明,相同条件下,稠油黏度大小、残炭值和沥青质含量从大到小顺序均为:塔里木稠油2、塔里木稠油1、塔里木稠油3;塔里木稠油2的芳碳率(fA)最高,塔里木稠油3及塔里木稠油1的芳碳率很接近。3种稠油的缩合指数(C.I.)差别不大。对同一种稠油,数均相对分子质量,结构参数CT、HT、fA、CA、RA、RT、RN、CN、C.I.从大到小顺序均为:沥青质、胶质、芳香分、饱和分。

关 键 词:稠油  组分  结构参数

Average Structure Parameter in Tarim Heavy Oils and Their Sub-Fractions
WEN Ping,WANG Xiaodan,GONG Lei,CUI Min,LI Chuan,HAO Haiying,DENG Wenan.Average Structure Parameter in Tarim Heavy Oils and Their Sub-Fractions[J].Journal of Petrochemical Universities,2013(5):6-9.
Authors:WEN Ping  WANG Xiaodan  GONG Lei  CUI Min  LI Chuan  HAO Haiying  DENG Wenan
Affiliation:1( 1. College of Chemical Engineering, China University of Petroleum, Qingdao Shandong 266555, China ; 2. Lenghu Oilfield , PetroChina Qinghai Oilfield Company, Haixi Qinghai 816300, China 3. Oil Production Technology Institute, PetroChina Dagang Oilfield Company, Tianjin 300280, China 4. College of Science, China University of Petroleum, Qingdao Shandong 266555, China)
Abstract:Heavy oils of Tarim LG-1, Tarim LG-2 and Tarim LG-3 were separated into four sub-fractions which are saturate, aromatic, resin and n-C7 asphaltene. Average structural parameters of heavy oil and their fractions were analyzed and computed. The results show that in the same condition, the viscosity size, carbon residue value and asphaltene content in order for all the size is Tarim LG-3, Tarim LG-1, Tarim LG-2. Aromatic carbon rate (fA) is the highest in Tarim LG-2, which approaching in Tarim LG-1 and Tarim LG-2. The condensation index(CI. ) of heavy oils are closely. The same trend of average molecular weight, CT, HT, fA, CA ,RA ,RT ,RN, CN, C I. has the size order which is asphaltene, resin, aromatic, saturate.
Keywords:Heavy oil  Sub-fraction  Structure parameter
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