Effect of aluminum content on mechanical properties of hydrogenated Mg–Al magnesium alloys

The mechanical properties of hydrogenated Mg–Al magnesium alloys with various aluminum content were investigated. The ductility, yield strength (YS) and ultimate tensile strength (UTS) of the hydrogenated material decreased while the hardness increased with increasing the aluminum content. Microscopic observations of cross-sections of hydrogenated specimens with various Al content revealed that hydrogen cracks extended deeply as the Al content in the Mg–Al alloys increased. Moreover, X-ray diffraction (XRD) analysis revealed that MgH₂ and AlH₃ hydrides are formed during hydrogenation and were found to contribute to hydrogen embrittlement of Mg–Al alloys. However, the embrittled zone was observed to be larger at the fracture surface of Mg–15Al alloy than that of Mg–5Al alloy. Moreover, the fracture surface of Mg–30Al alloy exhibited completely brittle fracture after hydrogenation.