| 高碳烯烃氢甲酰化研究进展 |
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| 引用本文： | 马占华,刘雪暖,杨国华.高碳烯烃氢甲酰化研究进展[J].化学工业与工程,2006,23(3):265-270. |
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| 作者姓名： | 马占华 刘雪暖 杨国华 |
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| 作者单位： | 中国石油大学(华东)化学化工学院,山东,东营,257061 |
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| 摘 要： | 水/有机两相催化体系被成功应用于低碳烯烃氢甲酰化反应.对于水溶性差的高碳烯烃，其氢甲酰化反应速度远远低于低碳烯烃.本文论述了近年来铑催化高碳烯烃氢甲酰化反应的研究和开发进展，其新型配体和新催化体系的研究开发一直是该领域的研究热点.主要涉及两相反应体系中的水溶性膦配体以及均相催化剂固相化、氟两相催化、非离子液体催化体系和超临界CO2中的氢甲酰化反应等几种新型反应体系.
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| 关 键 词： | 氢甲酰化 水溶性膦配体 担载水相催化剂 多相反应体系 |
| 文章编号： | 1004-9533（2006）03-0265-06 |
| 收稿时间： | 2005-06-10 |
| 修稿时间： | 2005年6月10日 |
Review on Hydroformylation of Higher Olefins |
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| MA Zhan-hua,LIU Xue-nuan,YANG Guo-hua.Review on Hydroformylation of Higher Olefins[J].Chemical Industry and Engineering,2006,23(3):265-270. |
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| Authors: | MA Zhan-hua LIU Xue-nuan YANG Guo-hua |
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| Affiliation: | College of Chemistry and Chemical Engineering, China University of Petroleum, Shandong Dongying 257061, China |
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| Abstract: | Water-soluble rhodium-phosphine complexes have been successfully applied in lower olefin hydroformylation. For higher olefin that has poor solubility in water, the hydroformylation reaction rate is much less than short-chain alkenes. This review covers the recent advances in Rh-catalysed hydroformylation of higher olefin, most of investigations in this field focus on the synthesis of new effective phosphine ligands and new catalysis systems. In particular, the developments of new-style reaction system, such as water-soluble phosphine in two-phase catalysis system, the supported catalysts,fluorous biphase system, non-aqueous ionic liquids catalysis and hydroformylation in supercritical carbon dioxide were mainly introduced in this paper. |
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| Keywords: | hydroformylation water-soluhle phosphine ligand supported aqueous phase catalysts multiphase reaction system |
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