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用即弃聚丙烯纺粘法非织造布的可光降解研究
引用本文:刘青山,周思远,赵耀明,薛孝川.用即弃聚丙烯纺粘法非织造布的可光降解研究[J].产业用纺织品,2006,24(9):7-11.
作者姓名:刘青山  周思远  赵耀明  薛孝川
作者单位:1. 华南理工大学高分子材料系,广州,510640
2. 广东省化学纤维研究所,广州,510245
摘    要:通过在聚丙烯中加入掺杂1%(质量分数)Cu2+的锐钛矿型纳米TiO2作为光敏剂,采用纺粘法设备制备TiO2光敏剂含量为0.0%~1.2%的聚丙烯纺粘法非织造布。将其置于70℃、340 nm紫外光下进行光降解试验,研究样品的力学性能、结晶度和表面形态的变化。结果表明:在聚丙烯中加入Cu2+掺杂的锐钛矿型纳米TiO2,可以催化聚丙烯纺粘法非织造布的光氧化降解和加快降解速度,且在实验范围内光敏剂的含量越大,其光催化降解作用越强。

关 键 词:聚丙烯纺粘法非织造布  掺杂纳米TiO2  紫外光  光降解
文章编号:1004-7093(2006)09-0007-05
收稿时间:2006-03-22
修稿时间:2006-03-22

Study on Photo Degradable Polypropylene Spun-bonded Nonwovens
Liu Qingshan,Zhou Siyuan,Zhao Yaoming,Xue Xiaochuan.Study on Photo Degradable Polypropylene Spun-bonded Nonwovens[J].Technical Textiles,2006,24(9):7-11.
Authors:Liu Qingshan  Zhou Siyuan  Zhao Yaoming  Xue Xiaochuan
Affiliation:1.Department of Polymer Materials Science and Technology, South China University of Technology;2. Chemical Fiber Research Institute of Guangdong Province
Abstract:1% wt.Cu~(2+) doped anatase nanoparticles were added into polypropylene as a photosensitizer.The blend was melt spun and heat bonded to prepare spun-bonded PP nonwovens,which contain 0.0%~1.2% wt.doped nano-TiO_2.Having been irradiated with 340 nm UV light at 70℃ for different(periods),the samples were studied by mechanical property analyses,DSC and SEM.It can be concluded that the Cu~(2+) doped anatase nanoparticles is an effective photosensitizer to the photo degradation of polypropylene spunbonded nonwovens,and the more the content of the photosensitizer,the stronger the photo catalysis effect.
Keywords:polypropylene spun-bonded nonwovens  doped nano-TiO2  UV light  photo degradation
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