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Co-pyrolysis of bituminous coal and biomass in a pressured fluidized bed
Authors:Yong Huang  Ningbo Wang  Qiaoxia Liu  Wusheng Wang  Xiaoxun Ma
Affiliation:1. School of Chemical Engineering, Northwest University, 229 North Taibai Road, Xi''an 710069, China;2. Hydrocarbon High-efficiency Utilization Technology Research Center of Yanchang Petroleum (Group) Co. Ltd., Xi''an 710075, China;3. Chemical Engineering Research Center of the Ministry of Education (MOE) for Advanced Use Technology of Shanbei Energy, Xi''an 710069, China;4. Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Xi''an 710069, China;5. Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi''an 710069, China;6. International Scientific and Technological Cooperation Base of the Ministry of Science and Technology (MOST) for Clean Utilization of Hydrocarbon Resources, Xi''an 710069, China
Abstract:An experimental study on co-pyrolysis of bituminous coal and biomass was performed in a pressured fluidized bed reactor. The blend ratio of biomass in the mixture was varied between 0 and 100 wt%, and the temperature was over a range of 550-650℃ under 1.0 MPa pressure with different atmospheres. On the basis of the individual pyrolysis behavior of bituminous coal and biomass, the influences of the biomass blending ratio, temperature, pressure and atmosphere on the product distribution were investigated. The results indicated that there existed a synergetic effect in the co-pyrolysis of bituminous coal and biomass in this pressured fluidized bed reactor, especially when the condition of bituminous coal and biomass blend ratio of 70:30 (w/w), 600℃, and 0.3 MPa was applied. The addition of biomass influenced the tar and char yields and gas and tar composition during co-pyrolysis. The tar yields were higher than the calculated values from individual pyrolysis of each fuel, and consequently the char yields were lower. The experimental results showed that the composition of the gaseous products was not in accordance with those of their individual fuel. The improvement of composition in tar also indicated synergistic effect in the co-pyrolysis.
Keywords:Bituminous coal  Biomass  Co-pyrolysis  Pressured fluidized bed  Synergistic effect  
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