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Removal of tannic acid from aqueous solution by magnetic carbohydrate natural polymer
Affiliation:1. Department of Environmental Sciences, Faculty of Meteorology, Environment and Arid Land Agriculture, King Abdulaziz University, Jeddah 21589, Saudi Arabia;2. Center of Excellent in Environmental Studies (CEES), King Abdulaziz University, Saudi Arabia;3. Central Metallurgical R&D Institute, Helwan Cairo 11421, Egypt;4. Chemistry Department, Faculty of Science, Minia University, Minia, Egypt;1. Department of Environmental Engineering, Konkuk University, Seoul 143-701, Korea;2. Green Technology Co., Ltd., 6F Hanam Venture Tower B/D, ChangWoo-Dong, HaNam-Si 465-120, GyeongGi-Do, Korea;3. Department of Advanced Technology Fusion, Konkuk University, Seoul 143-701, Korea;1. Department of Environment, Hamedan Branch, Islamic Azad University, Hamedan, Iran;2. Young Researchers & Elite Club, Hamedan Branch, Islamic Azad University, Hamedan, Iran;3. Department of Chemistry, Ilam University, Ilam, Iran;1. Physical Chemistry Department, Laboratory of Surface Chemistry and Catalysis, National Research Center, Dokki, Cairo, Egypt;2. Zoology Department, College of Science, King Saud University, Riyadh 11451, Kingdom of Saudi Arabia;3. Electron Microscope and Thin Films Department, National Research Center (NRC), El- Behooth Street, Giza 12622, Egypt;1. Department of Chemical Engineering, Chungnam National University, 220 Gung-Dong, Yuseong-Gu, Daejeon 305-764, Republic of Korea;2. Department of Fire and Disaster Protection Engineering, Woosong University, 17 JaYang-Dong, Dong-Gu, Daejeon 300-718, Republic of Korea
Abstract:Adsorptive removal of tannic acid (TA) form aqueous solution by synthesized magnetic lignocellulosic adsorbent was investigated. SEM, EDAX, and FTIR analysis were performed to characterize the magnetic saw dust (MSD). The effect of various operational parameters such as contact time, concentration and solution pH etc were studied. The optimum adsorption of TA was observed at pH 4. Results revealed that the Temkin isotherm model fitted well to the adsorption equilibrium data and obeyed the pseudo-second order kinetics model. The values of free energy change and activation energy suggested that physical forces were involved in the adsorption of TA onto MSD.
Keywords:Magnetic adsorbent  Tannic acid  Kinetics  Isotherm  Thermodynamics
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