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Reaction mechanism,kinetics and network structure of the DGEBA-DDS system
Authors:Marie-Florence Grenier-Loustalot  Philippe Grenier  Patrick Horny  Jean-Yves Chenard
Abstract:
Different techniques were used to analyse the reaction mechanisms and kinetics of the system 2,2-[4-(2,3-epoxypropyl)phenyl]propane polycondensed with 4,4′-sulphonyl-dianiline in the temperature range 100?185°C. The results show the role of catalysts, of stoichiometry and of curing cycles in the reaction mechanisms and paths. Based on chemical balances of residual epoxy groups, and of hydroxy and ether groups formed, we have shown the effect of these functions on the thermal properties of the material.
Keywords:kinetics  network  structure  epoxy resin  FTIR  NMR solid and liquid state  gelation  aromatic amines
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