High-mobility tetrathiafulvalene organic field-effect transistors from solution processing

We report on mobilities up to 3.6 cm²/V s in organic field-effect transistors (OFETs) with solution-processed dithiophene- and dibenzo-tetrathiafulvalene (DT- and DB-TTF) single crystals as active materials. In the devices, the channel length varies from 100 μm down to sub 100 nm, and the SiO₂ thickness is either 100 nm, 50 nm, or 20 nm. The devices exhibit excellent operation characteristics with an on/off-ratio exceeding 10⁶. Temperature dependent measurements between 50 and 400 K reveal a thermally activated transport with increased activation above 200 K. The mobility exhibits exponential activation with two distinct exponents.