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Preparation,microstructure and mechanical properties of MoAlB-0.15% Si ceramics with superior strength and toughness
Affiliation:1. State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi''an Jiaotong University, Xi''an, 710049, China;2. State Key Laboratory of Porous Metal Materials, Northwest Institute for Non-ferrous Metal Research, Xi''an, 710016, China
Abstract:MoAlB has been regarded as a promising high-temperature structural ceramic, but the strength and toughness are still insufficient in the practical application. In this work, MoAlB ceramic bulk with superior hardness, strength and toughness has been fabricated by adding 0.15 mol. % Si. The MoAlB-0.15Si bulk is composed of Si-doped MoAlB, Mo(Al, Si)2 and ultrafine Al2O3. The Vickers hardness ranges from 14.2 to 12.5 GPa with the tested load increasing from 10 to 200 N. The Vickers indentation remains the intact tetragonum in spite of the appearance of corner cracks, indicating the excellent damage tolerance. The flexural strength, fracture toughness and compressive strength of MoAlB-0.15Si are 518.46 MPa, 7.01 MPa m1/2 and 2.62 GPa, respectively, obviously superior to the present MoAlB polycrystalline bulk. Si doping, grain refinement, strengthening effect of ultrafine Al2O3 and phase transformation from Al8Mo3 to Mo(Al, Si)2 jointly account for the improvement of comprehensive properties of MoAlB bulk.
Keywords:MoAlB  Si addition  Hardness  Strength  Fracture toughness
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