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Performance of BaZrO3/Y2O3 dual-phase refractory applied to TiAl alloy melting
Affiliation:1. State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy & School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, PR China;2. Shanghai Special Casting Engineering Technology Research Center, Shanghai, 201605, PR China;3. Beijing Advanced Innovation Center for Materials Genome Engineering, Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing, 100083, PR China;4. School of Materials Science and Engineering, Shanghai Dianji University, Shanghai, 201306, PR China
Abstract:Vacuum induction melting is a potential process for the preparation of TiAl alloys with good homogeneity and low cost. But the crucial problem is a selection of high stability refractory. In this study, a BaZrO3/Y2O3 dual-phase refractory was prepared and its performance for melting TiAl alloys was studied and compared with that of a Y2O3 refractory. The results showed the dual-phase refractory consisted of BaZr1-xYxO3-δ and Y2O3(ZrO2), exhibited a thinner interaction layer (30 μm) than the Y2O3 refractory (90 μm) after melting the TiAl alloy. Although the TiAl alloys melted in the dual-phase and Y2O3 refractory exhibited similar oxygen contamination (<0.1 wt%), the alloy melted in the dual-phase refractory had smaller Y2O3 inclusion content and size than that in the Y2O3 refractory, indicating that the dual-phase refractory exhibited a better melting performance than the Y2O3 refractory. This study provides insights into the process of designing highly stable refractory for melting TiAl alloys.
Keywords:Barium zirconate  Yttrium  Dual-phase refractory  Titanium aluminum alloy  Induction melting
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