STUDY OF POSITRON ANNIHILATION ONE DIMENSION ANGULAR-CORRELATION RADIATION ON POLYCRYSTAL Na~+ CONDUCTOR Na_5Y_(1-x)Cr_xSi_4O_(12)

With positron annihilation radiation onedimension angular-correlation device,it ismeasured that positron annihilation radiationone dimension angular-correlation curves ofpolycrystal sodium ion conductor Na_5Y_(1-x)Cr_xSi_4O_(12)(NYCS)system.After electronmomentum distribution curves arenormalized,linear parameters arecalculated.The parameters H,W and Sshow the change of Na~+ ion vacancyconcentration in NYCS series samples.Theresults show that parameters H,W and S ofone dimension angular-correlation curves ofthose samples vary greatly with Cr_2O_3contents.With Cr_2O_3 content increasing,Hand S parameters increase,but W decreases,and reaches extremes at x=0.05;then withCr_20_3 adding continually,parameters H andS decrease gradually,parameter W increasesgradually.This shows that,in addtion toCr_2O_3,the conductivity has close relation

STUDY OF POSITRON ANNIHILATION ONE DIMENSION ANGULAR-CORRELATION RADIATION ON POLYCRYSTAL Na~+CONDUCTOR Na_5Y_(1_x)Cr_xSi_4O_(12)

With positron annihilation radiation one dimension angular-correlation device, it is measured that positron annihilation radiation one dimension angular-correlation curves of polycrystal sodium ion conductor Na5Y1-x CrxSi4O12 (NYCS) system. After electron momentum distribution curves are normalized, linear parameters are calculated. The parameters H, W and S show the change of Na+ ion vacancy concentration in NYCS series samples. The results show that parameters H, W and S of one dimension angular-correlation curves of those samples vary greatly with Cr2O3 contents. With Cr2O3 content increasing, H and S parameters increase, but W decreases, and reaches extremes at x=0.05; then with Cr2O3 adding continually, parameters H and S decrease gradually, parameter W increases gradually. This shows that, in addtion to Cr2O3, the conductivity has close relation with the concentration of Na+ ion vacancy.