| 分子筛固载西佛碱和四氢西佛碱铜配合物的合成和表征 |
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| 引用本文： | 王润平,索海云,毛树红,段秀琴.分子筛固载西佛碱和四氢西佛碱铜配合物的合成和表征[J].工业催化,2006,14(10):65-68. |
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| 作者姓名： | 王润平 索海云 毛树红 段秀琴 |
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| 作者单位： | 太原科技大学化学与生物工程学院，山西 太原 ;030021 |
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| 摘 要： | 合成了三种西佛碱H2L(H2L1=双水杨醛缩丙二胺，H2L2=双水杨醛缩环己二胺，H2L3=双水杨醛缩乙二胺)及相应的四氢西佛碱配体H2［H4］L，并与醋酸铜反应合成其铜配合物。采用自由配体法将金属铜配合物封装在Y型分子筛的超笼里，同时利用红外手段对其进行了表征。证明在环己烷氧化反应中Cu［H4］-Y比CuL-Y具有更高的反应活性。
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| 关 键 词： | 自由配体法 Y型分子筛 环己烷氧化 西佛碱 |
| 文章编号： | 1008-1143（2006）10-0065-04 |
| 收稿时间： | 2006-06-08 |
| 修稿时间： | 2006-06-29 |
Synthesis and characterization of copper(Ⅱ) complexes with skiff base and tetrahydro skiff base encapsulated in zeolite-Y |
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| WANG Run-ping,SUO Hai-yun,MAO Shu-hong,DUAN Xiu-qin.Synthesis and characterization of copper(Ⅱ) complexes with skiff base and tetrahydro skiff base encapsulated in zeolite-Y[J].Industrial Catalysis,2006,14(10):65-68. |
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| Authors: | WANG Run-ping SUO Hai-yun MAO Shu-hong DUAN Xiu-qin |
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| Affiliation: | School of Chemical & Biological Engineering, Taiyuan University of Science &Technology，Taiyuan 030021, China |
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| Abstract: | Three kinds of skiff bases,H_2L:H_2L_1=H_2Salpn,H_2L_2=H_2Salcyhexen,H_2L_3=H_2Salen,and their tetrahydro skiff base H_2(H_4)L were synthesized.Y zeolite encapsulated with CuL and(Cu(H_4)L) were prepared by flexible ligand method and characterized by FTIR.The experimental results showed that the Cu(H_4)L encapsulated in Y zeolite exhibited higher activity for cyclohexane oxidation with H_2O_2 than CuL encapsulated in Y zeolite. |
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| Keywords: | flexible ligand method Y zeolite cyclohexane oxidation skiff base |
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