A novel terpyridyl rhenium(II) complex – Synthesis,spectroscopic characterization and X-ray structure |
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| Affiliation: | 1. Department of Inorganic and Radiation Chemistry, Institute of Chemistry, University of Silesia, 9th Szkolna Street, 40-006 Katowice, Poland;2. Department of X-ray Crystallography and Crystal Chemistry, Institute of General and Ecological Chemistry, Technical University of Lodz, 116 Żeromski Street, 90-924 Łódź, Poland;3. Institute of Physics, University of Silesia, 4th Uniwersytecka Street, 40-006 Katowice, Poland;1. Facultad de Química, Pontificia Universidad Católica de Chile, Casilla 306, Santiago, Chile;2. Facultad de Ciencias, Universidad de Chile, Las Palmeras 3425, Santiago, Chile;1. Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018, PR China;2. College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, PR China;1. Institute of Physics, University of Tartu, W. Ostwald Str. 1, 50411, Tartu, Estonia;2. Institute of Physics of the Czech Academy of Sciences, Cukrovarnická 10/112, 162 00, Prague, Czech Republic;3. Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences, Konkoly-Thege M ut 29-33, H-1121, Budapest, Hungary;1. Instituto de Química e Biotecnologia, Universidade Federal de Alagoas, Campus A. C. Simões, Tabuleiro do Martins 57072-970, Maceió-AL, Brazil;2. Centro de Tecnologia da Informação Renato Archer, Divisão de Mostradores da Informação 13069-901, Campinas-SP, Brazil;3. Department of Chemistry, Loughborough University, LE11 3TU, Leicestershire, United Kingdom;1. Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, PR China;2. Department of Materials Science and Engineering, University of Toronto, 184 College Street, Toronto, Ontario M5S 3E4, Canada |
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| Abstract: | ![]()
The reaction of the [ReOBr3(PPh3)2] complex with 2,2′:6′,2″-terpyridine (terpy) in the presence of tripenylphosphine has been examined and novel [ReBr(terpy)(PPh3)2]ReO4 · H2O · CH3OH complex – has been obtained. It has been studied by IR, UV–vis spectroscopy and X-ray crystallography. |
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