High-dielectric-constant and low-loss microwave dielectric in the (1 − x)La(Mg0.5Ti0.5)O3-x(Ca0.8Sr0.2)TiO3 solid solution system |
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Authors: | Cheng-Liang Huang Jhih-Yong Chen |
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Affiliation: | Department of Electrical Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan |
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Abstract: | The microwave dielectric properties and microstructures of (1 − x)La(Mg0.5Ti0.5)O3-x(Ca0.8Sr0.2)TiO3 ceramics, prepared by a mixed oxide route, have been investigated. The forming of solid solutions was confirmed by the XRD patterns and the measured lattice parameters for all compositions. A near zero τf was achieved for samples with x = 0.5, although the dielectric properties varied with sintering temperature. The Q × f value of 0.5La(Mg0.5Ti0.5)O3-0.5(Ca0.8Sr0.2)TiO3 increased up to 1475 °C, after which it decreased. The decrease in dielectric properties was coincident with the onset of rapid grain growth. The optimum combination of microwave dielectric properties was achieved at 1475 °C for samples where x = 0.5 with a dielectric constant ?r of 47.12, a Q × f value of 35,000 GHz (measured at 6.2 GHz) and a τf value of −4.7 ppm/°C. |
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Keywords: | Crystal growth Dielectric response |
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