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Nafion/histidine functionalized carbon nanotube: High-performance fuel cell membranes
Authors:Mahsa S Asgari  Manouchehr Nikazar  Payam Molla-abbasi  Mohammad Mahdi Hasani-Sadrabadi
Affiliation:1. Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran;2. Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, Tehran, Iran;3. Laboratoire de Microsystemes (LMIS4), Institute of Microengineering, École Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland
Abstract:Here we show preparation and characterization of a new type of composite membrane based on Nafion®/histidine modified carbon nanotube by imidazole groups (Im-CNT), for direct methanol fuel cell (DMFC) applications. Due to the presence of this imidazole-based amino acid on the surface of CNT, new electrostatic interactions can be formed in the interface of Nafion® and Im-CNT. Physical characteristics of these nanocomposite membranes are investigated by water uptake, methanol permeability, ion exchange capacity, proton conductivity, as well as fuel cell performance results.
Keywords:Direct methanol fuel cell  Nanocomposite proton exchange membranes  Imidazole functionalized carbon nanotube  Fuel cell efficiency
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