| 原位聚合ZDMA与炭黑并用补强POE的研究 |
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| 引用本文： | 李甜甜,谢尊虎,商元元,邱桂学.原位聚合ZDMA与炭黑并用补强POE的研究[J].特种橡胶制品,2012,33(1):37-40. |
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| 作者姓名： | 李甜甜 谢尊虎 商元元 邱桂学 |
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| 作者单位： | 青岛科技大学 橡塑材料与工程教育部重点实验室,山东 青岛,266042 |
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| 摘 要： | 研究了原位聚合甲基丙烯酸锌(ZDMA)与炭黑并用以及体系的填充量、ZDMA理论生成量、ZnO/MMA摩尔比对聚烯烃弹性体(POE)硫化胶性能的影响.结果表明,加入炭黑改善了胶料的拉伸永久变形,当ZDMA与炭黑的用量为50～60份时,填料分散好,对胶料的补强效果显著.ZDMA理论用量为30～40份、ZnO/MMA摩尔比为0.75左右时,胶料的综合力学性能最好.
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| 关 键 词： | POE ZDMA 炭黑 原位聚合 |
Study on the Properties of POE Reinforced with the In-situ Polymerized ZDMA /Carbon Black |
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| LI Tian-tian
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XIE Zun-hu
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SHANG Yuan-yuan
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QIU Gui-xue.Study on the Properties of POE Reinforced with the In-situ Polymerized ZDMA /Carbon Black[J].Special Purpose Rubber Products,2012,33(1):37-40. |
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| Authors: | LI Tian-tian XIE Zun-hu SHANG Yuan-yuan QIU Gui-xue |
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| Affiliation: | (Qingdao University of Science and Technology,Qingdao 266042,China) |
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| Abstract: | The effect of in-situ synthesized ZDMA/ carbon black blending,filling amount,ZDMA amount and ZnO/MMA mole ratio on mechanical properties of vulcanized polyolefin elastomer(POE) were studied.The results showed that the permanent set was obviously improved with carbon black.When black carbon and ZDMA was 50~60phr,the filler dispersion and reinforcing effect was good.The POE vulcanizates had good mechanical properties when the ZDMA amount was 30~40phr,ZnO/MMA mole ratio was 0.75. |
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| Keywords: | POE ZDMA carbon black in-situ polymerization |
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