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动态三螺杆挤出机制备热塑性硫化胶的研究
引用本文:赵艳志,瞿金平,何和智.动态三螺杆挤出机制备热塑性硫化胶的研究[J].现代塑料加工应用,2007,19(1):46-48.
作者姓名:赵艳志  瞿金平  何和智
作者单位:华南理工大学聚合物新型成型装备国家工程研究中心,聚合物成型加工工程教育部重点实验室,广东,广州,510640
基金项目:国家高技术研究发展计划(863计划);高等学校博士学科点专项科研项目
摘    要:对比分析了动态热塑性硫化胶(TPV)的加工设备,着重介绍了附加振动力场的三螺杆反应挤出机的结构特点以及利用该机进行三元乙丙橡胶/聚丙烯(EPDM/PP)的动态全硫化,对制品的物理力学性能和微观结构分别进行了测试分析和电镜扫描。结果表明,振动力场作用下EPDM/PP共混体系反应挤出动态硫化加工可有效地实现动态硫化反应、硫化橡胶的粉碎和分散以及相态反转,振动力场的作用明显提高了TPV性能。

关 键 词:振动力场  动态全硫化  三元乙丙橡胶  聚丙烯  热塑性硫化橡胶  动态三螺杆反应挤出机
修稿时间:2006-07-21

Preparation of Thermoplastic Vucanization Rubber with Dynamic Three-screw Extruder
Zhao Yanzhi,Qu Jinping,He Hezhi.Preparation of Thermoplastic Vucanization Rubber with Dynamic Three-screw Extruder[J].Modern Plastics Processing and Applications,2007,19(1):46-48.
Authors:Zhao Yanzhi  Qu Jinping  He Hezhi
Affiliation:National Engineering Research Center of Novel Equipment for Polymer Processing, Key Laboratory of Polymer Processing Engineering of Ministry of Education, South China University of Technology, Guangzhou,Guangdong, 510640
Abstract:The processing equipments of dynamic TPV are analyzed.The structural char- acteristics of dynamic three-screw reactive extruder under vibration force field are chiefly in- troduced.EPDM/PP blends are fully dynamically vulcanized by means of the new-style ex- truder.The mechanical properties are analyzed and the microstructure of the TPV samples is scanned with SEM.The results show that dynamic vulcanization processing of reactive ex- trusion of the EPDM/PP blends under vibration force field can effectively achieve dynamic vulcaniation reaction,vulcanization rubber comminution and dispersion as well as phase re- version.Vibration force field obviously improves TPV properties.
Keywords:vibration force field  full dynamic vulcanization  ethylene/propylene terpolymer  polypropylene  thermoplastic vulcanization rubber  dynamic three-screw reactive extruder
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