Morphology of poly(hexamethylene oxide) fractions

The supermolecular structure of crystallised molecular weight fractions of poly(hexa-methylene oxide), covering the molecular weight range (M) 4.5. × 10³ to 8. 5 × 10⁴, was studied by polarised light microscopy and small angle light scattering. Different forms were observed as a function of molecular weight and crystallisation temperatures. Perfect spherulites are formed after rapid crystallisation, and these forms deteriorate as both the molecular weight and crystallisation temperature increase. The morphology in the isothermal crystallisation region corresponds to an intermediate state which represents a transition from spherulites to hedrites.