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Vaporization kinetics of Sb_2S_3 in argon fluid
引用本文:杨勇,华一新. Vaporization kinetics of Sb_2S_3 in argon fluid[J]. 中国有色金属学会会刊, 2003, 13(1)
作者姓名:杨勇  华一新
作者单位:Department of Metallurgy,Kunming University of Science and Technology,Kunming 650093,China,Department of Metallurgy,Kunming University of Science and Technology,Kunming 650093,China
基金项目:Project( 5 996 40 0 1)supportedbytheNationalNaturalScienceFoundationofChina
摘    要:1 INTRODUCTIONAntimonytrisulfideisoneofthemostpracticallysig nificantmaterialsamongtheantimonysulfidesinthein dustry.Atpresent ,intheproductionofantimonyfromsulfideores ,antimonytrisulfideisvolatilizedintogasphaseandthenoxidizedbyoxygeninthegasphase .Thea…


Vaporization kinetics of Sb2S3 in argon fluid
YANG Yong,HUA Yi-xin. Vaporization kinetics of Sb2S3 in argon fluid[J]. Transactions of Nonferrous Metals Society of China, 2003, 13(1)
Authors:YANG Yong  HUA Yi-xin
Abstract:The vaporization kinetics of antimony trisulfide in argon fluid was studied with thermogravimetry at 8731 173 K. A theoretical model was developed to calculate the overall rate constant and the mass transfer coefficient in gas phase. The experimental results show that the vaporization rate is enhanced with increasing temperature and argon flow-rate. The evaporation rate is mainly controlled by mass transport in the gas phase. The apparent activation energy for the process is found to be 55.54 kJ/mol. It is demonstrated that the mass transfer coefficient in gas phase is decreased with increasing temperature.
Keywords:Sb 2S 3  vaporization  kinetics
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